Article is devoted to valuation the possibility of using new synthesized compounds as anticorrosive pigments in natural drying alkyd primers. Technical and physical properties of new pigments based on transition metal compounds of different nature (oxides, phosphates, car-bides, complex compounds) and phosphorus-containing pigments was investigated, new reci-pes of primers was designed, physical, mechanical and protective properties of coatings was investigated. Dependence of the anticorrosive properties of the synthesized pigments, primers and coatings was established from their chemical nature