Environmental molecular beam experiments are used to examine water
interactions with liquid methanol films at temperatures from 170 K to 190 K. We
find that water molecules with 0.32 eV incident kinetic energy are efficiently
trapped by the liquid methanol. The scattering process is characterized by an
efficient loss of energy to surface modes with a minor component of the
incident beam that is inelastically scattered. Thermal desorption of water
molecules has a well characterized Arrhenius form with an activation energy of
0.47{\pm}0.11 eV and pre-exponential factor of 4.6 {\times} 10^(15{\pm}3)
s^(-1). We also observe a temperature dependent incorporation of incident water
into the methanol layer. The implication for fundamental studies and
environmental applications is that even an alcohol as simple as methanol can
exhibit complex and temperature dependent surfactant behavior.Comment: 8 pages, 5 figure
