We wish to report a simple procedure for the preparation of 5-substituted-thienopyridin-7-ones and 7-substituted-1,6-naphthyridin-5(6H)-ones, in good yields, from the dianions of 3-methylthiophene-2-carboxylic and 2-methylnicotinic acids on treatment with nitriles.Brun Sanchez, Eva Maria, [email protected] ; Gil Grau, Salvador, [email protected] ; Parra Alvarez, Margarita, [email protected]