The effect of the electrode potential on Surface Enhanced Raman Scattering (SERS) intensities of 2-methylpyrazine (2MP) recorded under resonant charge transfer (CT) conditions is analyzed by using a simple theoretical model [1] in which the macroscopic surface charge in the metal is modeled by several metallic clusters with different number of silver atoms (n) and charges (q), [Agn]q. Two and three linear silver atoms with zero and positive and negative charges, respectively, bounded to the 2MP through the nitrogen atom, have been taking into account.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tec
