A Lamb-shift polarimeter, which has been built for a fast determination of
the polarization of protons and deuterons of an atomic-beam source and which is
frequently used in the ANKE experiment at COSY-J\"ulich, is shown to be an
excellent device for atomic-spectroscopy measurements of metastable hydrogen
isotopes. It is demonstrated that magnetic and electric dipole transitions in
hydrogen can be measured as a function of the external magnetic field, giving
access to the full Breit-Rabi diagram for the 22S1/2 and the 22P1/2
states. This will allow the study of hyperfine structure, g factors and the
classical Lamb shift. Although the data are not yet competitive with
state-of-the-art measurements, the potential of the method is enormous,
including a possible application to anti-hydrogen spectroscopy.Comment: 6 pages, 7 figures, accepted by European Physical Journal