"I dispersi al largo della Libia sarebbero un centinaio. Tra i profughi approdati a Pozzallo c'era anche un gatto. Salvata una bimba di 14 mesi aggrappata a una tavola C'erano anche 81 donne e 133 minori tra i 449 migranti siriani, palestinesi ed egiziani arrivati a Pozzallo, nel ragusano, le cui operazioni di sbarco sono terminate intorno alle due della scorsa notte. Con il gruppo degli immigrati c'era anche un gatto, sottoposto poi a visita veterinaria per verificare che non fosse portatore..

Dahmani, Rahma

Dekanski, Dragana

Grgurić-Šipka, Sanja

Grubišić, Sonja

Mitić, Dragana

Nikolić, Stefan

Tošić, Jelena

Vidičević, Sašenka

Đorđević, Ivana S.

Journal of Coordination Chemistry

Supplementary material for: [https://doi.org/10.1080/00958972.2018.1553298]Related to accepted version: [http://cherry.chem.bg.ac.rs/handle/123456789/2934]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/3758

Cherry - Repository of the Faculty of Chemistry;  University of Belgrade

  
 
 
Supplementary material for the article: 
 
 
Nikolić, S.; Grgurić-Šipka, S.; Djordjević, I. S.; Dahmani, R.; Dekanski, D.; Vidičević, S.; 
Tošić, J.; Mitić, D.; Grubišić, S. Half-Sandwich Ruthenium(II)-Arene Complexes: Synthesis, 
Spectroscopic Studies, Biological Properties, and Molecular Modeling. Journal of 
Coordination Chemistry 2019, 72 (1), 148–163. 
https://doi.org/10.1080/00958972.2018.1553298  
1 
Supplementary Information 
 
Half-sandwich ruthenium(II)-arene complexes: Synthesis, spectroscopic studies, 
biological properties and molecular modeling 
 
STEFAN NIKOLIĆ, SANJA GRGURIĆ-ŠIPKA, IVANA S. DJORDJEVIĆ, RAHMA DAHMANI, 
DRAGANA DEKANSKI, SAŠENKA VIDIČEVIĆ, JELENA TOŠIĆ, DRAGANA MITIĆ and 
SONJA GRUBIŠIĆ* 
 
 
 
Table of contents 
 
IR spectra .................................................................................................... Figures S1 and S2 
NMR spectra ...................................................................................................... Figures S3-S6 
NMR spectra in DMSO during 48 h ........................................................... Figures S7 and S8 
NMR spectra in DMSO/D2O .................................................................... Figures S9 and S10 
UV-Vis spectra ........................................................................................ Figures S11 and S12 
Mass spectra ............................................................................................ Figures S13 and S14 
2 
 
 
Figure S1. IR spectrum of complex 1. 
3 
 
Figure S2. IR spectrum of complex 3. 
4 
 
Figure S3. 
1
H NMR (500 MHz, DMSO-d6) spectrum of complex 1. 
5 
 
Figure S4. 
13
C NMR (125 MHz, DMSO-d6) spectrum of complex 1. 
6 
 
Figure S5. 
1
H NMR (200 MHz, DMSO-d6) spectrum of complex 3. 
7 
 
Figure S6. 
13
C NMR (50 MHz, DMSO-d6) spectrum of complex 3. 
8 
 
Figure S7. 
1
H NMR (500 MHz, DMSO-d6) spectra of complex 1 during 48 h. 
9 
 
Figure S8. 
1
H NMR (500 MHz, DMSO-d6) spectra of complex 3 during 48 h. 
10 
 
Figure S9. 
1
H NMR (500 MHz, DMSO-d6/D2O) spectra of complex 1. 
11 
 
Figure S10. 
1
H NMR (500 MHz, DMSO-d6/D2O) spectra of complex 3. 
12 
 
Figure S11. Experimental UV-Vis spectra, calculated the electronic transitions and molecular 
orbitals of complex 1. The black line with marked numbers represent experimental UV-Vis 
curve; Colored curves represent calculated transitions where H-2, H-3, H-4 correspond to 
HOMO-2, HOMO-3, HOMO-4 while L+1, L+2, L+3, L+4 stand for LUMO+1, LUMO+2, 
LUMO+3, LUMO+4. 
13 
 
Figure S12. Experimental UV-Vis spectra, calculated the electronic transitions and molecular 
orbitals of complex 3. The black line with marked numbers represent experimental UV-Vis 
curve; Colored curves represent calculated transitions where H-1, H-5, H-6 correspond to 
HOMO-1, HOMO-5, HOMO-6 while L+1, L+2, L+3, L+6 stand for LUMO+1, LUMO+2, 
LUMO+3, LUMO+6. 
14 
 
Figure S13. Mass spectra of complex 1. 
15 
 
Figure S14. Mass spectra of complex 3. 


English

Supplementary material for the article: Nikolić, S.; Grgurić-Šipka, S.; Djordjević, I. S.; Dahmani, R.; Dekanski, D.; Vidičević, S.;  Tošić, J.; Mitić, D.; Grubišić, S. Half-Sandwich Ruthenium(II)-Arene Complexes: Synthesis,  Spectroscopic Studies, Biological Properties, and Molecular Modeling. Journal of  Coordination Chemistry 2019, 72 (1), 148–163.  https://doi.org/10.1080/00958972.2018.1553298

ENIGMUR

OpenEdition

In Sicilia sbarcati 800 migranti, altri seicento in arrivo. Ad Augusta i 24 morti dell'ultimo naufragio, repubblica.it, 27/08/2014

Faculty of Chemistry Repository - Cherry

    Supplementary material for the article:   Nikolić, S.; Grgurić-Šipka, S.; Djordjević, I. S.; Dahmani, R.; Dekanski, D.; Vidičević, S.; Tošić, J.; Mitić, D.; Grubišić, S. Half-Sandwich Ruthenium(II)-Arene Complexes: Synthesis, Spectroscopic Studies, Biological Properties, and Molecular Modeling. Journal of Coordination Chemistry 2019, 72 (1), 148–163. https://doi.org/10.1080/00958972.2018.1553298  1 Supplementary Information  Half-sandwich ruthenium(II)-arene complexes: Synthesis, spectroscopic studies, biological properties and molecular modeling  STEFAN NIKOLIĆ, SANJA GRGURIĆ-ŠIPKA, IVANA S. DJORDJEVIĆ, RAHMA DAHMANI, DRAGANA DEKANSKI, SAŠENKA VIDIČEVIĆ, JELENA TOŠIĆ, DRAGANA MITIĆ and SONJA GRUBIŠIĆ*    Table of contents  IR spectra .................................................................................................... Figures S1 and S2 NMR spectra ...................................................................................................... Figures S3-S6 NMR spectra in DMSO during 48 h ........................................................... Figures S7 and S8 NMR spectra in DMSO/D2O .................................................................... Figures S9 and S10 UV-Vis spectra ........................................................................................ Figures S11 and S12 Mass spectra ............................................................................................ Figures S13 and S14 2   Figure S1. IR spectrum of complex 1. 3  Figure S2. IR spectrum of complex 3. 4  Figure S3. 1H NMR (500 MHz, DMSO-d6) spectrum of complex 1. 5  Figure S4. 13C NMR (125 MHz, DMSO-d6) spectrum of complex 1. 6  Figure S5. 1H NMR (200 MHz, DMSO-d6) spectrum of complex 3. 7  Figure S6. 13C NMR (50 MHz, DMSO-d6) spectrum of complex 3. 8  Figure S7. 1H NMR (500 MHz, DMSO-d6) spectra of complex 1 during 48 h. 9  Figure S8. 1H NMR (500 MHz, DMSO-d6) spectra of complex 3 during 48 h. 10  Figure S9. 1H NMR (500 MHz, DMSO-d6/D2O) spectra of complex 1. 11  Figure S10. 1H NMR (500 MHz, DMSO-d6/D2O) spectra of complex 3. 12  Figure S11. Experimental UV-Vis spectra, calculated the electronic transitions and molecular orbitals of complex 1. The black line with marked numbers represent experimental UV-Vis curve; Colored curves represent calculated transitions where H-2, H-3, H-4 correspond to HOMO-2, HOMO-3, HOMO-4 while L+1, L+2, L+3, L+4 stand for LUMO+1, LUMO+2, LUMO+3, LUMO+4. 13  Figure S12. Experimental UV-Vis spectra, calculated the electronic transitions and molecular orbitals of complex 3. The black line with marked numbers represent experimental UV-Vis curve; Colored curves represent calculated transitions where H-1, H-5, H-6 correspond to HOMO-1, HOMO-5, HOMO-6 while L+1, L+2, L+3, L+6 stand for LUMO+1, LUMO+2, LUMO+3, LUMO+6. 14  Figure S13. Mass spectra of complex 1. 15  Figure S14. Mass spectra of complex 3. 

http://cherry.chem.bg.ac.rs/bitstream/id/16393/Half-Sandwich_Ruthenium_sup_2019.pdf

In Sicilia sbarcati 800 migranti, altri seicento in arrivo. Ad Augusta i 24 morti dell'ultimo naufragio, repubblica.it, 27/08/2014

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