Constable, Edwin

Phillips, D

Raithby, PR

The reaction of 4'-phenyl-2,2':6', 2"-terpyridine I with nickel(II) chloride gives a 1: 1 adduct which we have structurally characterised and shown to be comprised of two species of stoichiometry {Ni(I)Cl-2}; the first is a five-coordinate [Ni(I)Cl-2] complex and the other is a dinuclear species containing two six-coordinate nickel centres [(I)ClNi(mu-Cl)(2)Ni(I)Cl]. (C) 2002 Elsevier Science B.V. All rights reserved

Nickel(II) chloride adducts of 4 '-phenyl-2,2 ': 6 ',2 ''-terpyridine

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