preparationofpolyisobutylenebtertbutylacrylatebytransformationoflivingcarbocationicpolymerizationintoradicalpolymerization

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Publication date
1 January 2006
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Abstract

使用BCl3／CH2Cl2／DTBP／IB反应体系实现了异丁烯的正离子聚合，得到末端为硼氧烷基的聚异丁烯，其与苯基溴化镁发生金属转移反应，生成末端为二苯基硼烷的聚异丁烯，其在常温下与氧气发生氧化反应，生成碳氧自由基，从而引发丙烯酸叔丁酯的自由基聚合，得到异丁烯和丙烯酸叔丁酯的嵌段聚合物

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