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非催化气固反应动力学热分析方法与仪器
Authors
余剑
刘文钊
+3 more
岳君容
张光义
许光文
Publication date
1 January 2011
Publisher
Abstract
准确测量近本征反应速率和计算反应动力学参数是热化学工程和应用化学工程领域的重要研究问题。以热重为代表的传统热分析方法与仪器在非催化气固反应的测试与分析中得到了广泛应用, 形成了许多典型的非等温反应分析方法与模型方程。本研究概述了现有热分析的方法原理及在气固反应分析中存在的缺陷, 剖析了自主研发的利用微型流化床反应器强化反应传热与传质, 实现气固快速混合与加热、低扩散抑制、微分化的近本征反应的思想。系统总结了基于该思想研制的微型流化床反应分析仪在分解、热解、燃烧(氧化)、还原、吸收等典型非催化气固反应中的应用特性, 并展示了相应的等温动力学参数结果
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Institutional Repository of Institute of Process Engineering, CAS (IPE-IR)
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oai:ir.ipe.ac.cn:122111/31404
Last time updated on 05/12/2019
Institutional Repository of Institute of Process Engineering, CAS (IPE-IR)
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:ir.ipe.ac.cn:122111/31402
Last time updated on 05/12/2019