HETEROCYCLIZATION WITH IMINIUM SALTS AND N-YLIDES

Abstract

Novel 2,3a,6a-triazaphenalene and 1-thia-2a,5a-diaza-acenaphthene ring systems were synthesized and their ring transformation reactions affording polycycles with bridgehead nitrogen atom were investigated. 1,3-Dipolar cycloaddition of isoquinoline N-ylides with azomethines and olefines were studied and the regio- and stereoselectivity of the reaction were proved by structure elucidation and quantum chemical calculations

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