Complexes composed of fullerenes and metal elements offer important examples as new nanomaterials in the field of materials design. In the collisions between C^-_ and Li^+ in plasma state, there is a possibility that the endohederal fullerene, Li@C_ is created as well as Li@C_ and so on. To study this phenomenon theoretically, we perform an all-electron mixed basis ab initio molecular dynamics simulation at 1, 000K which was developed by ourselves. When Li^+ with the kinetic energy ～5eV hits the center of a six-membered ring of C^-_, an endohedral complex, Li@C_ is created. This direcet insertion process is possible because the ionic radius of Li^+ is shorter then the radius of a six-membered ring. However, if either the kinetic energy is lower or the collision occurs off-center, the Li^+ ion stays outside and C_ is deformed by the shock
