Linde, R. van der

Loontjens, J.A.

Nuyken, O.

Rieß, G.

English

The cationic polymerization of 2-chloro ethyl vinylether (CEVE) is initiated by 1-iodo-1-(2-methylpropyloxy)ethane/(n-Bu)4NClO4. The monomer is consumed following first order kinetics. Molar masses are controlled by the ratio [M]:[I]. A rather narrow molar mass distribution is obtained. These observations and the linear conversion-molar mass relationship indicate the living nature of the CEVE polymerization. Poly(CEVE) was converted into poly(2-(1-pyrrolidonyl)-1-ethylvinylether) by the complete nucleophilic substitution of chlorine by the anion of pyrrolidone

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   University of GroningenSynthesis of Poly(2-Chloro Ethyl Vinylether) and Its DerivativesNuyken, O.; Rieß, G.; Loontjens, J.A.; Linde, R. van derPublished in:Journal of Macromolecular Science. Part A: Pure and Applied ChemistryIMPORTANT NOTE: You are advised to consult the publisher's version (publisher's PDF) if you wish to cite fromit. Please check the document version below.Document VersionPublisher's PDF, also known as Version of recordPublication date:1995Link to publication in University of Groningen/UMCG research databaseCitation for published version (APA):Nuyken, O., Rieß, G., Loontjens, J. A., & Linde, R. V. D. (1995). Synthesis of Poly(2-Chloro EthylVinylether) and Its Derivatives. Journal of Macromolecular Science. Part A: Pure and Applied Chemistry,32(1), 217-226.CopyrightOther than for strictly personal use, it is not permitted to download or to forward/distribute the text or part of it without the consent of theauthor(s) and/or copyright holder(s), unless the work is under an open content license (like Creative Commons).The publication may also be distributed here under the terms of Article 25fa of the Dutch Copyright Act, indicated by the “Taverne” license.More information can be found on the University of Groningen website: https://www.rug.nl/library/open-access/self-archiving-pure/taverne-amendment.Take-down policyIf you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediatelyand investigate your claim.Downloaded from the University of Groningen/UMCG research database (Pure): http://www.rug.nl/research/portal. For technical reasons thenumber of authors shown on this cover page is limited to 10 maximum.Download date: 06-06-2022Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011Downloaded By: [Dutch Library Consortium (UKB) - Dekker Titles only] At: 12:28 2 March 2011

Synthesis of Poly(2-Chloro Ethyl Vinylether) and Its Derivatives

https://pure.rug.nl/ws/files/3275336/1995MacromolRepANuyken2.pdf

Synthesis of Poly(2-Chloro Ethyl Vinylether) and Its Derivatives

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