Unusual Lattice Parameters Behavior for La1.9Ca0.1NiO4+δ at the Temperatures below Oxygen Loss

Abstract

In this work, we studied the structural features of La1.9Ca0.1NiO4.11, which is considered a promising cathode material for intermediate temperature solid-oxide fuel cells (IT-SOFC). The effect of different pretreatments on the structural characteristics of the sample was studied using X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) in order to elucidate the origin of a peculiar change of lattice parameters observed earlier during in situ XRD studies. The XRD studies have shown that anisotropic broadening for reflections with a high Miller index l appears after tempering of a quenched (from 1100◦C) sample at 250◦C. This temperature is too low for the release/incorporation of oxygen into the structure but is sufficient for oxygen migration inside the structure. The HRTEM assisted us in revealing differences in the defect structure after different pretreatments. Based on obtained results, the following possible explanation was proposed. Observed additional microstrains and non-oriented planar defects as well as a decrease in the coherent scattering region size in the [00l] direction are caused by the non-homogeneous redistribution of interstitial oxygen in the structure during tempering. © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).Funding: The reported study was funded within the framework of budget project for Synchrotron radiation facility SKIF, Boreskov Institute of Catalysis. In the part of samples characterization by HRTEM technique the work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis