Piezoelectric materials are employed in a wide range of sensing devices. At present, the vast majority
of piezoelectric materials used for industrial applications are ceramic and exhibit a high lead content in
their composition. However, the development of lead-free piezoelectric materials is attracting great
attention in recent years, with the aim of enabling technologies that are environmentally friendly. This
paper discusses the computational design of microstructured lead-free polymer-based piezoelectric
nanocomposites suitable for production by 3D printing. Results are presented and further analyzed for
various configurations using BaTiO3 inclusions in polymeric matrices enriched with the addition of
carbon nanotubes (CNT). By incorporating carbon nanotubes in the matrix, we anticipate a quite
significant improvement in the piezoelectric response of the composite, through simultaneous
hardening of the matrix and improvement in its permittivity.Ministerio de Economía y Competitividad de España y el Fondo Europeo de Desarrollo Regional (FEDER) RTI2018-094945-B-C21Ministerio de Economía y Competitividad de España y el Fondo Europeo de Desarrollo Regional (FEDER) DPI2017-89162-