Kinetic Study of the Chelate Ligand Unwrapping Reactions of Sterically Hindered Gold (III) Complexes

Abstract

The complexes [Au(Et2dien_H)Br]PF6, [AU(Me4dien_H)Br]Pf6, and [Au(Et3dien_H)Br]PF6 have been sunthesized and a kinetic study of their conjugate acids performed. This paper centers on the direct replacement of the tridentate ligang on the complex by bromide ion

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