The magnetic structure of Ni(CH2CO2NH2)2 2 H2O has been determined by the analysis of neutron-diffraction data from powder and single-crystal samples. Ni(CH2CO2NH2)2 2 H2O orders at a Néel temperature of 0.88 K. The magnetic structure consists of antiferromagnetically coupled layers having a canted ferromagnetic ordering within layers, with a moment of (2.33 ± 0.14)μB per Ni2+ ion. The magnetic unit cell is composed of two crystallographic unit cells, and contains four nickel atoms. The moment direction is not simply related to either crystalline or molecular symmetry axes
