Mr=402.4, orthorhombic, P212~2 l, a=
4-946 (1), b= 15.887 (2), c=26.555 (2)A, V=
2086.7 (5) A 3, Z = 4, D x = 1.28 gcm -a, Cu Ka, 2 =
1.5418/k, B = 6.868 cm -1, F(000) = 848, T= 293 K,
final R =0.054 for 648 observed reflections. The
molecule is propeller shaped. The benzoyl groups act as
protecting groups and the phenyl group is a base
substitute. The crystal structure does not involve any
intermolecular stacking interactions between the phenyl
groups. The molecules pack in typical herring-bone-like
arrays. The sugar has a fl-D configuration with
C(2')-endo-C(3')-exo pucker (2T3), pseudorotation
angle P = 172 (2) °, degree of pucker r m = 39 (2) °