The effect of charge composition, casting section thickness and inoculation on gray cast iron microstructure

Abstract

U ovom diplomskom radu je analiziran utjecaj različitih sastava uloška za izradu taline, debljine stijenke odljevka i cijepljenja na mikrostrukturu sivog lijeva. Izrađene su 3 taline sivog lijeva gotovo istog kemijskog sastava. Korišteni su sljedeći udjeli sirovog željeza (SŽ), čeličnog otpada (ČO), povratnog sivog lijeva (PSL) i SiC u ulošku: talina 1 (39,4 % SŽ, 10 % ČO, 49,2 % PSL, 0,6 % SiC), talina 2 (9,9 % SŽ, 38,8 % ČO, 47,9 % PSL, 1,6 % SiC) i talina 3 (0 % SŽ, 0 % ČO, 99,2 % PSL, 0,06 % SiC). Od svake taline odlivena su 2 stepenasta odljevka sa stijenkama debljina 5, 10, 20, 45 i 65 mm, jedan necijepljen i jedan cijepljen (dodatak cjepiva u mlaz taline tijekom ulijevanja u kalup iznosio je 0,23 mas. %). Dobiveni rezultati pokazuju da tip, veličina i raspodjela grafitnih listića u analiziranim stijenkama nisu u značajnijoj mjeri ovisili o sastavu uloška. Debljina stijenke imala je veliki utjecaj na tip, veličinu i raspodjelu grafitnih listića, izlučivanje karbida te strukturu metalne osnove. S povećanjem debljine stijenke mijenja se tip grafitnih listića od D i E preko B do A tipa. Karbidi su pronađeni u rubnom dijelu stijenke debljine 5 mm. Udio ferita u metalnoj osnovi povećavao se sa smanjenjem brzine hlađenja te sa povećanjem udjela grafitnih listića D i E tipa. Cijepljenjem je značajno smanjen udio karbida u rubnom dijelu stijenke debljine 5 mm. U sredini stijenke debljine 5 mm te stijenkama debljine 10 do 65 mm cijepljenjem je povećan udio grafitnih listića A tipa te su eliminirani grafitni listići B, D i E tipa ili je njihov udio značajno smanjen (učinak ovisi o debljini stijenke).The effect of different charge compositions for melt production, casting section thickness and inoculation on the gray cast iron microstructure was analysed in this graduate thesis. Three gray cast iron melts of almost the same chemical composition were made. The following shares of pig iron (PI), steel scrap (SS), gray iron return (GIR) and SiC in charge were used: melt 1 (39.4 % PI, 10 % SS, 49.2 % GIR, 0.6 % SiC), melt 2 (9.9 % PI, 38.8 % SS, 47.9 % GIR, 1.6 % SiC) and melt 3 (0 % PI, 0 % SS, 99.2 % GIR, 0.06 % SiC). Two stepped castings with walls thicknesses of 5, 10, 20, 45 and 65 mm are casted from each melt, one uninoculated and one inoculated (the addition of inoculant in the melt stream during the pouring in the mold was 0.23 wt.%). The obtained results show that the type, size and distribution of graphite flakes in the analysed walls did not significantly depend on the composition of the charge. The wall thickness had a great influence on the type, size and distribution of graphite flakes, carbides precipitation and the structure of the metal matrix. The type of graphite flakes is changed from D and E, over B to A type with increasing wall thickness. Carbides were found in the edge part of the wall thickness of 5 mm. The percentage of ferrite in the metal matrix increased with decreasing the cooling rate and with increasing the proportion of graphite flakes D and E type. Inoculation significantly reduced the proportion of carbides in the edge part of the wall thickness of 5 mm. In the middle of the wall thickness of 5 mm and the walls thicknesses of 10 to 65 mm the inoculation resulted in an increase in the proportion of graphite flakes A type. In addition, the graphite flakes B, D and E types were eliminated or their proportion was significantly reduced (effect depends on the wall thickness)

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