Extremely polysubstituted magnetic material based on magnetoplumbite with a hexagonal structure: Synthesis, structure, properties, prospects

Abstract

Crystalline high-entropy single-phase products with a magnetoplumbite structure with grains in the µm range were obtained using solid-state sintering. The synthesis temperature was up to 1400 °C. The morphology, chemical composition, crystal structure, magnetic, and electrodynamic properties were studied and compared with pure barium hexaferrite BaFe 12 O 19 matrix. The polysubstituted high-entropy single-phase product contains five doping elements at a high concentration level. According to the EDX data, the new compound has a formula of Ba(Fe6Ga1.25In1.17Ti1.21Cr1.22Co1.15)O19. The calculated cell parameter values were a = 5.9253(5) Å, c = 23.5257(22) Å, and V = 715.32(9) Å3. The increase in the unit cell for the substituted sample was expected due to the different ionic radius of Ti/In/Ga/Cr/Co compared with Fe3+. The electrodynamicmeasurements were performed. The dielectric and magnetic permeabilities were stable in the frequency range from 2 to 12 GHz. In this frequency range, the dielectric and magnetic losses were??0.2/0.2. Due to these electrodynamic parameters, this material can be used in the design of microwave strip devices. © 2019 by the authors. Licensee MDPI, Basel, Switzerland.Funding: The work was supported by the Russian Science Foundation, project No. 18-73-10049