Three complementary methods have been implemented in the code Denovo that accelerate neutral particle transport calculations with methods that use leadership-class computers fully and effectively: a multigroup block (MG) Krylov solver, a Rayleigh quotient iteration (RQI) eigenvalue solver, and a multigrid in energy preconditioner. The multigroup Krylov solver converges more quickly than Gauss Seidel and enables energy decomposition such that Denovo can scale to hundreds of thousands of cores. The new multigrid in energy preconditioner reduces iteration count for many problem types and takes advantage of the new energy decomposition such that it can scale efficiently. These two tools are useful on their own, but together they enable the RQI eigenvalue solver to work. Each individual method has been described before, but this is the first time they have been demonstrated to work together effectively. RQI should converge in fewer iterations than power iteration (PI) for large and challenging problems. RQI creates shifted systems that would not be tractable without the MG Krylov solver. It also creates ill-conditioned matrices that cannot converge without the multigrid in energy preconditioner. Using these methods together, RQI converged in fewer iterations and in less time than all PI calculations for a full pressurized water reactor core. It also scaled reasonably well out to 275,968 cores
