Radioassay of Gadolinium-Loaded Liquid Scintillator and Other Studies for the LZ Outer Detector

Abstract

It is now well established that over 80\% of the matter in our Universe is comprised of a non-luminous substance known as dark matter. By far the most popular dark matter candidate is the weakly interacting massive particle (WIMP). Attempting to discover the nature of WIMP dark matter through direct detection has been a central activity of experimental physics for at least the last 20 years. To date, no conclusive signal consistent with WIMP interactions has been observed.The LZ (LUX-ZEPLIN) experiment is a second generation direct dark matter detector under construction one mile underground in the Davis Laboratory of the Sanford Underground Research Facility (SURF) in Lead, South Dakota, USA. LZ will use a 7 tonne central liquid xenon target, arranged in a dual-phase time projection chamber (TPC), to seek evidence for nuclear recoils from a hypothesized galactic flux of WIMPs. Two active detector elements will surround the TPC: a layer of liquid xenon, the xenon skin, optimized to detect $\gamma$'s, and the outer detector (OD), optimized to detect neutrons. Together, these detectors will tag backgrounds to the sought-after WIMP signal and characterize the background environment around LZ.The OD is comprised of acrylic tanks filled with 17.3 tonnes of LAB-based gadolinium-loaded liquid scintillator (GdLS) that will surround the central cryostat of LZ in a near-hermetic fashion. Its primary function will be to tag neutron single-scatter events in the liquid xenon which could mimic a WIMP dark matter signal. I summarize simulation studies of the OD expected performance as a neutron veto and expected light collection.The rate of single background pulses in the OD is also discussed. The three primary sources of rate in the OD are identified as: LZ detector components, $\gamma$-rays from the Davis Laboratory walls, and the radioimpurities in the GdLS. The radioimpurities in the GdLS are particularly troublesome because the OD is sensitive to both the $\alpha$ and $\beta$/$\gamma$ decays of these isotopes. To meet the requirements for the OD, the radioimpurity levels in the GdLS must be kept below $\lesssim0.07$ mBq/kg. This background level corresponds to a rate of $\approx50$ Hz above an energy threshold of 100 keV.I report on the design and performance of the ``Screener", a small liquid scintillator detector consisting of $\approx23$ kg of the GdLS to be used in the OD. The Screener was operated in the ultra-low-background environment of the former LUX water shield in the Davis Laboratory at SURF for radioassay of the GdLS. Careful selection of detector materials and use of ultra-low-background PMTs allows the measurement of a variety of radioimpurities. The $^{14}\textrm{C}$/$^{12}\textrm{C}$ ratio in the scintillator is measured to be $(2.83\pm0.06\textrm{(stat.)}\pm0.01\textrm{(sys.)}) \times 10^{-17}$. Use of pulse shape discrimination allows the concentration of isotopes throughout the $^{238}\textrm{U}$, $^{235}\textrm{U}$, and $^{232}\textrm{Th}$ chains to be measured by fitting the collected spectra from $\alpha$ and $\beta$ events. It is found that equilibrium is broken in the $^{238}\textrm{U}$ and $^{232}\textrm{Th}$ chains and that a significant portion of the contamination in the GdLS results from decays in the $^{227}\textrm{Ac}$ subchain of the $^{235}\textrm{U}$ series.Predictions for the singles rate in the OD are presented. The rate from radioimpurities above 100 keV in the GdLS is estimated to be $97.5\pm6.3$ Hz, with $65.0\pm1.4$ Hz resulting from $\alpha$-decays