Some Reactions of Diphenyletyleneimine and Attempts to Prepare Aminoethenes

Abstract

Ozone had no effect on diphenylethyleneimine. The benzoyl derivative was prepared in pyridine by the action of benzoyl chloride. In dilute sodium hydroxide the same reagent formed α-β-diphenyl-β-chloroethylamine. This compound was changed to benzoyl diphenylethyleneimine by heating with alcoholic sodium ethylate. On being heated to 225° diphenylethyleneimine rearranged to benzalbenzylamine. A number of experiments were tried in an attempt to prepare aminoethenes but the results were not conclusive

    Similar works