Corrosion behavior of CuAlMn and CuAlMnNi alloy in 0.9% NaCl solution

Abstract

Corrosion behavior of CuAlMn and CuAlMnNi alloy ribbons, produced by melt spinning method, were investigated by electrochemical methods such as open circuit potential measurement, linear and potentiodynamic polarization method. Investigations were performed in deaerated 0.9% NaCl solution (T = 37 °C pH = 7.4). Results of electrochemical investigations have shown that CuAlMnNi alloy have higher values of polarization resistance and smaller values of corrosion current density, but in higher anodic potentials region anodic current density for CuAlMn is lower than for CuAlMnNi alloy which indicates higher dissolution of CuAlMnNi alloy. After polarization measurements CuAlMn and CuAlMnNi ribbon surfaces were investigated with light microscope and with SEM/EDS analysis and results have shown that CuAlMnNi alloy is prone to pitting corrosion, while the surface of CuAlMn alloy is partially covered with corrosion product without existence of pits

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