Positron annihilation spectroscopy (PAS) is a technique for measuring the length of time that a positron exists after being injected into a specific material. Lifetime measurements have been used for studying defects in metals. These imperfections affect the localized electron densities which in turn influence the lifetime of the positron before annihilation occurs. Electron density differences are also associated with surfaces. This paper describes the PAS technique and shows a correlation between positron annihilation intensities and surface areas of some fumed amorphous silicas