An efficient photoanode is a prerequisite for a viable solar fuels technology. The challenges to realizing an efficient photoanode include the integration of a semiconductor light absorber and a metal oxide electrocatalyst to optimize corrosion protection, light trapping, hole transport, and photocarrier recombination sites. To efficiently explore metal oxide coatings, we employ a high-throughput methodology wherein a uniform BiVO_4 film is coated with 858 unique metal oxide coatings covering a range of metal oxide loadings and the full (Ni–Fe–Co–Ce)O_x pseudoquaternary composition space. Photoelectrochemical characterization of the photoanodes reveals that specific combinations of metal oxide composition and loading provide up to a 13-fold increase in the maximum photoelectrochemical power generation for oxygen evolution in pH 13 electrolyte. Through mining of the high-throughput data we identify composition regions that form improved interfaces with BiVO_4. Of particular note, integrated photoanodes with catalyst compositions in the range Fe_((0.4–0.6))Ce_((0.6–0.4))O_x exhibit high interface quality and excellent photoelectrochemical power conversion. Scaled-up inkjet-printed electrodes and photoanodic electrodeposition of this composition on BiVO_4 confirms the discovery and the synthesis-independent interface improvement of (Fe–Ce)O_x coatings on BiVO_4
