Mathematical models of phase transitions in solids lead to the variational problem, minimize ∫_ΩW (Du) dx, where W has a multi-well structure, i.e. W = 0 on a multi-well set K and W > 0 otherwise. We study this problem in two dimensions in the case of equal determinant, i.e. for K = SO(2)U_1 ∪...∪ SO(2)U_k or K = O(2)U_1 ∪...∪ O(2)Uk for U_1,...,U_k ∈ M^(2×2) with det U_i = δ in three dimensions when the matrices U_i are essentially two-dimensional and also for K = SO(3)Û_1 ∪...∪ SO(3)Û_k for U_1,...,U_k ∈ M^(3×3) with (adj U_i^TU_i)33 = δ^2, which arises in the study of thin films. Here, Û_i denotes the (3×2) matrix formed with the first two columns of U_i. We characterize generalized convex hulls, including the quasiconvex hull, of these sets, prove existence of minimizers and identify conditions for the uniqueness of the minimizing Young measure. Finally, we use the characterization of the quasiconvex hull to propose 'approximate relaxed energies', quasiconvex functions which vanish on the quasiconvex hull of K and grow quadratically away from it