The orbital motion of electrons in a three-dimensional solid can generate a
pseudoscalar magnetoelectric coupling θ, a fact we derive for the
single-particle case using a recent theory of polarization in weakly
inhomogeneous materials. This polarizability θ is the same parameter
that appears in the "axion electrodynamics" Lagrangian ΔLEM=(θe2/2πh)E⋅B, which is known to describe the
unusual magnetoelectric properties of the three-dimensional topological
insulator (θ=π). We compute θ for a simple model that accesses
the topological insulator and discuss its connection to the surface Hall
conductivity. The orbital magnetoelectric polarizability can be generalized to
the many-particle wavefunction and defines the 3D topological insulator, like
the IQHE, in terms of a topological ground-state response function.Comment: 4 pages; minor changes resulting from a change in one referenc