Some Aspects of the Photoelectrochemical Effect at the Mercury - Aqueous Solution Interphase

Abstract

The emissive properties of a polarized mercury surface in contact. with aqueous solutions of electron acceptors is discussed. The proportionality between photocurrent and light intensity is experimentally verified; the origin of the residual current is discussed, and the potentialities of a photoelectrochemical method of study· of the properties of intermediates and radicals is illustrated for carbon dioxide

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