Allylic Cations in Solvolysis. A Case of Non-Participation

Abstract

The rate constants and secondary deuterium Isotope ef\u27fects are measured in the solvo\u27lysis of various allyHc p-nitrobenzoates. The obtained results are explained by differences in inductive effects o>f vardous groups in the side-chain. These results are in keeping with the stepwise mechanism according to which neighboiring group n- and n-paxticiipation is not revealed in the studied solvCJ!lytic reactions

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