The entropy production (inside the volume bounded by a photosphere) of main-sequence stars, subgiants, giants, and supergiants is calculated based on B–V photometry data. A non-linear inverse relationship of thermodynamic fluxes and forces as well as an almost constant specific (per volume) entropy production of main-sequence stars (for 95% of stars, this quantity lies within 0.5 to 2.2 of the corresponding solar magnitude) is found. The obtained results are discussed from the perspective of known extreme principles related to entropy production