Polymer blends of poly(D,L-lactic-co-glycolic acid), PDLLGA, and triblock polycaprolactonepoly(dimethylsiloxane)-polycaprolactone (PCL-PDMS-PCL) copolymer, TEGOMER, were obtained by coprecipitation from their chloroform mixed solutions into methanol and were characterized by differential scanning calorimetry (DSC), Fourier transform infrared (FTIR), degradation tests and scanning electron microscopy (SEM). Binary blends of PDLLGA/TEGOMER were found to be partially miscible according to DSC measurements and FTIR analysis. Stressstrain results showed that addition of TEGOMER improved significantly the overall toughness of PDLLGA. Degradation of PDLLGA/TEGOMER blends was investigated in phosphate buffered saline at pH = 7.4 and 37 °C, and the morphology of the blends during degradation was examined by scanning electron microscopy
