This communication describes the synthesis of: (i) non toxic and low cost nanocrystalline
electrode materials which can be advantageously prepared at low temperature; (ii) highly
conductive electrolyte membranes formed by the nano-encapsulation within a poly
(acrylonitrile)-based polymer matrix of a solution of LiPF6 in organic solvants. The
performances of rechargeable PLR (Plastic Lithium Rechargeable) batteries using the
above mentioned components are presented