The aim of this work is to investigate the development of nanofiber mats, based on intrinsically conductive polymers (ICPs), which show simultaneously a high electrical conductivity and mandatory insoluble water properties. In particular, the nanofibers, thanks to their properties such as high surface area, porosity, and their ability to offer a preferential pathway for electron flow, play a crucial role to improve the essential characteristics ensured by ICPs. The nanofiber mats are obtained by electrospinning process, starting from a polymeric solution made of polyethylene oxide (PEO) and poly(styrene sulfonate) (PEDOT:PSS). PEO is selected not only as a dopant to increase the electrical/ionic conductivity, as deeply reported in the literature, but also to ensure the proper stability of the polymeric jet, to collect a dried nanofiber mat. Moreover, in the present work, two different treatments are proposed in order to induce crosslinking between PEO chains and PEDOT:PSS, made insoluble into water which is the final sample. The first process is based on a heating treatment, conducted at 130°C under nitrogen atmosphere for 6 h, named the annealing treatment. The second treatment is provided by UV irradiation that is effective to induce a final crosslinking, when a photoinitiator, such as benzophenone, is added. Furthermore, we demonstrate that both crosslinking treatments can be used to verify the preservation of nanostructures and their good electrical conductivity after water treatment (i.e., water resistance). In particular, we confirm that the crosslinking method with UV irradiation results to being more effective than the standard annealing treatment. Indeed, we demonstrate that the processing time, required to obtain the final crosslinked nanofiber mats with a high electrical conductance, results to being smaller than the one needed during the heating treatment
