We show that the bordism group of closed 3-manifolds with positive scalar
curvature (psc) metrics is trivial by explicit methods. Our constructions are
derived from scalar-flat K{\"a}hler ALE surfaces discovered by Lock-Viaclovsky.
Next, we study psc 4-manifolds with metric singularities along points and
embedded circles. Our psc null-bordisms are essential tools in a
desingularization process developed by Li-Mantoulidis. This allows us to prove
a non-existence result for singular psc metrics on enlargeable 4-manifolds with
uniformly Euclidean geometry. As a consequence, we obtain a positive mass
theorem for asymptotically flat 4-manifolds with non-negative scalar curvature
and low regularity.Comment: 28 pages, 2 figures, comments welcom