CORE
🇺🇦
make metadata, not war
Services
Services overview
Explore all CORE services
Access to raw data
API
Dataset
FastSync
Content discovery
Recommender
Discovery
OAI identifiers
OAI Resolver
Managing content
Dashboard
Bespoke contracts
Consultancy services
Support us
Support us
Membership
Sponsorship
Community governance
Advisory Board
Board of supporters
Research network
About
About us
Our mission
Team
Blog
FAQs
Contact us
1,10-diaza-18-crown-ether, modified by phosphonate pendant arms - Synthesis, structure, and picrate extraction properties
Authors
Khusainova N.
Krivolapov D.
+3 more
Litvinov I.
Rybakov S.
Safin D.
Publication date
1 January 2008
Publisher
Abstract
Reaction of O,O′-diisopropyl-3-methyl-1,2-butadienylphosphonate with 1,10-diaza-18-crown-6 in the presence of a catalytic amount of iPrONa leads to the new crown-ether derivative, containing phosphonate pendant arms (L). The structure of the compound obtained was investigated by single crystal X-ray diffraction analysis, IR, 1H and 31P{1H} NMR spectroscopy, and microanalysis. In the crystal structure the side arms of L are in an anti disposition relative to the macrocyclic cavity. It was established that phosphorylation of 1,10-diaza-18-crown-6 by allenylphosphonate results in an increase of extraction of NaPic and KPic, whereas LiPic and NH4Pic are extracted practically in the same level. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA
Similar works
Full text
Open in the Core reader
Download PDF
Available Versions
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/140928
Last time updated on 07/05/2019