CORE
🇺🇦
make metadata, not war
Services
Services overview
Explore all CORE services
Access to raw data
API
Dataset
FastSync
Content discovery
Recommender
Discovery
OAI identifiers
OAI Resolver
Managing content
Dashboard
Bespoke contracts
Consultancy services
Support us
Support us
Membership
Sponsorship
Community governance
Advisory Board
Board of supporters
Research network
About
About us
Our mission
Team
Blog
FAQs
Contact us
Coordination mode of the nickel(II) cation with N-diisopropoxyphosphinyl-p- bromothiobenzamide
Authors
Babashkina M.
Baranov S.
+6 more
Hahn F.
Kozlowski H.
Safin D.
Shakirova E.
Sokolov F.
Szyrwiel Ł.
Publication date
1 January 2008
Publisher
Abstract
Reaction of the potassium salt of N-diisopropoxyphosphinyl-p- bromothiobenzamide p-BrC6H4C(S)NHP(O)(OiPr)2 (HL) with Ni(NO3)2 in aqueous EtOH leads to complex of formula [Ni(HL-O)2(L-O,S)2] (1). The structure of 1 was investigated by single crystal X-ray diffraction analysis, IR, 1H and 31P{1H} NMR spectroscopy, MALDI and microanalysis. The nickel(II) ion in 1 has a tetragonal-bipyramidal environment, (O ax)2(Oeq)2(Seq) 2, with two neutral ligand molecules coordinated in axial positions through the oxygen atoms of the P=O groups. The equatorial plane of bipyramide is formed by two anionic ligands involving 1,5-O,S-coordination mode. The chelating ligands are bound in trans configuration. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA
Similar works
Full text
Open in the Core reader
Download PDF
Available Versions
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/101390
Last time updated on 07/05/2019
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/140929
Last time updated on 07/05/2019