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Nitrogen control in nanodiamond produced by detonation shock-wave-assisted synthesis
Authors
Jelezko F.
Khomich A.
+8 more
Orlinskii S.
Shenderova O.
Shiryaev A.
Sulyanov S.
Turner S.
Van Tendeloo G.
Vlasov I.
Wrachtrup J.
Publication date
1 January 2011
Publisher
Abstract
Development of efficient production methods of nanodiamond (ND) particles containing substitutional nitrogen and nitrogen-vacancy (NV) complexes remains an important goal in the nanodiamond community. ND synthesized from explosives is generally not among the preferred candidates for imaging applications owing to lack of optically active particles containing NV centers. In this paper, we have systematically studied representative classes of NDs produced by detonation shock wave conversion of different carbon precursor materials, namely, graphite and a graphite/hexogen mixture into ND, as well as ND produced from different combinations of explosives using different cooling methods (wet or dry cooling). We demonstrate that (i) the N content in nanodiamond particles can be controlled through a correct selection of the carbon precursor material (addition of graphite, explosives composition); (ii) particles larger than approximately 20 nm may contain in situ produced optically active NV centers, and (iii) in ND produced from explosives, NV centers are detected only in ND produced by wet synthesis. ND synthesized from a mixture of graphite/explosive contains the largest amount of NV centers formed during synthesis and thus deserves special attention. © 2011 American Chemical Society
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Kazan Federal University Digital Repository
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oai:dspace.kpfu.ru:net/140615
Last time updated on 07/05/2019
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/100037
Last time updated on 07/05/2019