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Acid-base properties of α-aminomethylphosphine oxides
Authors
Cherkasov R.
Davletshin R.
+4 more
Devyatov F.
Garifzyanov A.
Kurnosova N.
Rahmaeva A.
Publication date
1 January 2012
Publisher
Abstract
Abstract-Ionization constants of a series of aminomethylphosphine oxides and respective amino precursors, as well as their isostructural amino phosphonates in water-2-propanol or water medium were determined. The main regularities of the effect of the phosphoryl group on the protolytic equilibria involving mono- and bisphosphorylated amines and diamines were found. The environment effect on the ionization constants of hydrophilic aminophosphoryl compounds and amines was estimated quantitatively. The relationship between the dissociation constants of aminophosphoryl compounds and related constants of amino precursors in the framework of the principle of linearity of free energies was demonstrated. ©Pleiades Publishing, Ltd., 2012
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Kazan Federal University Digital Repository
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oai:dspace.kpfu.ru:net/138583
Last time updated on 07/05/2019
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/98383
Last time updated on 07/05/2019