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Substituted benzaldehydes in the darzens condensation with alkyl dihaloacetates
Authors
Berdnikov E.
Gorbunova E.
+6 more
Gubaidullin A.
Hamamoto H.
Komiyama T.
Litvinov I.
Mamedov V.
Tsuboi S.
Publication date
1 January 2006
Publisher
Abstract
The Darzens reaction of dihaloacetic acid esters with aromatic aldehydes produces either arylhaloglycidic or arylhalopyruvic esters depending on the nature of the substituent in the aromatic ring. Alkyl p- methoxyphenylchloropyruvates undergo spontaneous intermolecular cyclocondensation to form pyranone or furanone derivatives depending on the character of the alkyl fragment. © 2006 Springer Science+Business Media, Inc
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Last time updated on 07/05/2019