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Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes] 2(bpy)4}Br2
Authors
Dobrynin A.
Gerasimova T.
+4 more
Katsyuba S.
Sinyashin O.
Trofimova E.
Yakhvarov D.
Publication date
1 January 2013
Publisher
Abstract
The reaction of cobalt dibromide hexahydrate with 2,2'-bipyridine (bpy) and mesitylphosphinic acid MesP(O)(OH)H (Mes = = 2,4,6-trimethylphenyl) under solvothermal synthesis conditions leads to a new dinuclear cobalt(ii) complex {Co2[μ-O2P(H)Mes]2- (bpy) 4}Br2 formed by two bridging {μ-O2P(H)Mes}- ligands. X-ray crystal structure analysis of the complex displayed that cobalt ions have distorted octahedral coordination and are doubly bridged by two mesitylphosphinato ligands. © 2013 Mendeleev Communications. All rights reserved
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Last time updated on 07/05/2019