CORE
🇺🇦
make metadata, not war
Services
Services overview
Explore all CORE services
Access to raw data
API
Dataset
FastSync
Content discovery
Recommender
Discovery
OAI identifiers
OAI Resolver
Managing content
Dashboard
Bespoke contracts
Consultancy services
Support us
Support us
Membership
Sponsorship
Community governance
Advisory Board
Board of supporters
Research network
About
About us
Our mission
Team
Blog
FAQs
Contact us
Pd[tBuNH(S)NHP(O)(OiPr)2-S]2Cl2 complex as air- and moisture-stable catalyst for palladium catalyzed suzuki cross-coupling reaction
Authors
Babashkina M.
Safin D.
Publication date
1 January 2009
Publisher
Abstract
A highly efficient Suzuki cross-coupling reaction between phenyl bromide and phenylboronic acid catalyzed by the palladium complex Pd[tBuNH(S)NHP(O) (OiPr)2-S]2Cl2 in acetonitrile, toluene, THF or DMF has been investigated. The bases we have employed for this reaction were Na2CO3, K2CO3 or Cs 2CO3. It was established that using DMF and K 2CO3 at 100 °C shows excellent yields of the product at the catalyst amount of 0.1 mmol. The cross-coupling reactions of iodo- and chloro-benzene with phenylboronic acid were also investigated. The influence of the halide nature was as expected. © 2009 Springer Science+Business Media, LLC
Similar works
Full text
Open in the Core reader
Download PDF
Available Versions
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/137611
Last time updated on 07/05/2019