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Mechanistic aspects of reactions of triphenylphosphine with electron-deficient alkenes in acetic acid solution
Authors
Fatkhutdinov A.
Galkin V.
+5 more
Il'In A.
James B.
Salin A.
Sobanov A.
Sotov E.
Publication date
1 January 2013
Publisher
Abstract
Kinetic data provide evidence that proton transfer to the carbanion centre of a phosphonium zwitterion is the rate-determining step in quarternization reactions of triphenylphosphine with electron-deficient alkenes in acetic acid solution. This conclusion is based on the third-order rate equation, the reactivity of the alkenes, and solvent isotope effects in deuteroacetic acid. Copyright © 2013 John Wiley & Sons, Ltd
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Last time updated on 07/05/2019