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Addition of tetrachloromethane to alkenes, catalyzed by Pt(II) complexes
Authors
Khusnutdinova Y.
Osipova O.
Solomonov B.
Zazybin A.
Publication date
1 January 2005
Publisher
Abstract
Platinum(II) complexes [dichlorobis(triphenylphosphine)platinum(II), dichlorobis(tri-m-tolylphosphine)platinum(II), dichloro(2,9-dimethyl-1,10-N, N′-phenanthroline)platinum(II), etc.] showed catalytic activity in addition of tetrachloromethane across the double bond in 1-hexene, 1-heptene, 1-octene, 1-decene, and cyclohexene. The stability of the platinum catalysts was evaluated by GLC, gas chromatography-mass spectrometry, and 31P NMR and IR spectroscopy; the kinetic relationships of the addition reactions were determined. A reaction mechanism involving formation of trichloromethyl radical was suggested. A correlation was revealed for the first time between the catalytic activity of platinum, palladium, and rhodium complexes and the capability of these complexes to generate hexachloroethane. ©2005 Pleiades Publishing, Inc
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Kazan Federal University Digital Repository
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oai:dspace.kpfu.ru:net/98318
Last time updated on 07/05/2019
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/134995
Last time updated on 07/05/2019