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Electrochemically induced phosphorylation of alkenes
Authors
Babkin Y.
Kosachev I.
+3 more
Nikitin E.
Romakhin A.
Zagumennov V.
Publication date
1 January 1997
Publisher
Abstract
The processes of electrochemical phosphorylation of alkenes were investigated. It was found that anodically generated radical-cations of trialkyl phosphites, dialkyl trimethylsilyl phosphites, mono-and diamidophosphites were added to olefin molecules to give unsaturated alkenephosphonates. The anodic oxidation of tetraalkyl pyrophosphites proceeds with disintegration of initial radical-cations and leads to mixture alkane-and alkenephosphonates. Greater amounts of alkanephosphonates were formed during anodic oxidation of sodium (or lithium) dialkyl phosphites in the presence of alkenes. © 1997 Published by Elsevier Science Ltd
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Last time updated on 07/05/2019