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Reaction of acyl isocyanates with disubstituted amides and an investigation of hindered internal rotation in amidine molecules
Authors
Aganov A.
Arbuzov B.
Sofronova O.
Zobova N.
Publication date
1 January 1977
Publisher
Abstract
1. Trifluoroacetyl isocyanate reacts with dimethylformamide to form a six-membered cycloadduct. Trichloroacetyl isocyanate reacts similarly with dimethylacetamide. 2. Trifluoroacetyl isocyanate reacts with dimethylacetamide to form a substituted 1, 3, 5-dioxazin-4-one, and with dimethylbenzamide to form 1-trifluoroacetyl-2-phenyl-3, 3-dimethylamidine. 3. Using PMR spectroscopy, hindered internal rotation about the {Mathematical expression} bond in amidine molecules has been studied and its kinetic parameters determined. © 1977 Plenum Publishing Corporation
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Kazan Federal University Digital Repository
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oai:dspace.kpfu.ru:net/96446
Last time updated on 07/05/2019
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/132562
Last time updated on 07/05/2019