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Unusual reactivity of aliphatic and aromatic amines with bromoalkyl derivatives of thiacalix[4]arene in 1,3-alternate stereoisomeric form
Authors
Antipin I.
Burilov V.
+4 more
Gafiatullin B.
Ibragimova R.
Nugmanov R.
Solovieva S.
Publication date
1 January 2017
Publisher
Abstract
© ISUCT Publishing. For the first time a series of new cationic amphiphilic p-tert-butylthiacalix[4]arene derivatives adopting 1,3-alternate stereoisomeric form was synthesized by quaternization of several tertiary amines and N-heterocycles. The structure of all products was well-defined using modern physical technics. The influence of calixarene and amine sterical hindrances on reactivity is discussed
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Last time updated on 07/05/2019