© ISUCT Publishing. A consolidated review on the synthesis of lower rim tetrasubstituted thiacalixarenes and their self-assembly on  the soft surfaces contributed from our group is presented. The approaches for the synthesis of different types of tetra-O-substituted thiacalixarenes from the last 10 years are discussed. In addition, amphiphilic macrocycles in 1,3-alternate conformation form monolayers at the interface and are effectively embedded into the vesicles. Decorated by thiacalixarenes nanolayers and vesicles demonstrate a high selectivity towards specific analytes

Antipin I.

Burilov V.

Solovieva S.

Macroheterocycles

Kazan Federal University Digital Repository

Macroheterocycles 2017 vol.10 N2, pages 134-146Thiacalix[4]arene’s lower rim derivatives: Synthesis andsupramolecular propertiesSolovieva S., Burilov V., Antipin I.Kazan Federal University, 420008, Kremlevskaya 18, Kazan, RussiaAbstract© ISUCT Publishing.  A  consolidated review on the  synthesis  of  lower  rim tetrasubstitutedthiacalixarenes and their  self-assembly on the soft  surfaces contributed from our group ispresented.  The  approaches  for  the  synthesis  of  different  types  of  tetra-O-substitutedthiacalixarenes from the last 10 years are discussed. In addition, amphiphilic macrocycles in1,3-alternate conformation form monolayers at the interface and are effectively embedded intothe  vesicles.  Decorated  by  thiacalixarenes  nanolayers  and  vesicles  demonstrate  a  highselectivity towards specific analytes.http://dx.doi.org/10.6060/mhc170512aKeywordsAmphiphile, Molecular recognition, Synthetic methods, Thiacalix[4]areneReferences[1] Gutsche C.D. 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Thiacalix[4]arene’s lower rim derivatives: Synthesis and supramolecular properties

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Thiacalix[4]arene’s lower rim derivatives: Synthesis and supramolecular properties

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