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Concentration dependence of diffusion coefficients for supercritical carbon dioxide + naphthalene system
Authors
Arai Yasuhiko
Higashi Hidenori
+3 more
Iwai Yoshio
Nakamura Yuji
Oda Tsuyoshi
Publication date
1 March 2002
Publisher
'Elsevier BV'
Doi
Cite
Abstract
金沢大学大学院自然科学研究科生産プロセスThe concentration dependence of diffusion coefficients for naphthalene in supercritical carbon dioxide at 308.2K was measured by a pseudo steady-state solid dissolution method. The experimental diffusion coefficients were compared with the calculated results by the Darken equation including a thermodynamic factor and tracer diffusion coefficients of supercritical carbon dioxide and naphthalene. The thermodynamic factor in the Darken equation was determined by using several cubic equations of state. The calculated results by the Darken equation represent the concentration dependence of the experimental diffusion coefficients. © 2002 Elsevier Science B.V. All rights reserved
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Last time updated on 06/05/2019