We report high-resolution spectroscopy of 125 field stars previously observed
as part of the Sloan Digital Sky Survey and its program for Galactic studies,
the Sloan Extension for Galactic Understanding and Exploration (SEGUE). These
spectra are used to measure radial velocities and to derive atmospheric
parameters, which we compare with those reported by the SEGUE Stellar Parameter
Pipeline (SSPP). The SSPP obtains estimates of these quantities based on SDSS
ugriz photometry and low-resolution (R = 2000) spectroscopy. For F- and G-type
stars observed with high signal-to-noise ratios (S/N), we empirically determine
the typical random uncertainties in the radial velocities, effective
temperatures, surface gravities, and metallicities delivered by the SSPP to be
2.4 km/s, 130 K (2.2%), 0.21 dex, and 0.11 dex, respectively, with systematic
uncertainties of a similar magnitude in the effective temperatures and
metallicities. We estimate random errors for lower S/N spectra based on
numerical simulations.Comment: 37 pages, 6 tables, 6 figures, submitted to the Astronomical Journa