Heavy electrons and the symplectic symmetry of spin

Abstract

The recent discovery of two heavy fermion materials PuCoGa_{5} and NpPd_{5}Al_{2} which transform directly from Curie paramagnets into superconductors, reveals a new class of superconductor where local moments quench directly into a superconducting condensate. A powerful tool in the description of heavy fermion metals is the large N expansion, which expands the physics in powers of 1/N about a solvable limit where particles carry a large number (N) of spin components. As it stands, this method is unable to jointly describe the spin quenching and superconductivity which develop in PuCoGa_{5} and NpPd_{5}Al_{2}. Here, we solve this problem with a new class of large N expansion that employs the symplectic symmetry of spin to protect the odd time-reversal parity of spin and sustain Cooper pairs as well-defined singlets. With this method we show that when a lattice of magnetic ions exchange spin with their metallic environment in two distinct symmetry channels, they are able to simultaneously satisfy both channels by forming a condensate of composite pairs between between local moments and electrons. In the tetragonal crystalline environment relevant to PuCoGa_{5} and NpPd_{5}Al_{2} the lattice structure selects a natural pair of spin exchange channels, giving rise to the prediction of a unique anisotropic paired state with g-wave symmetry. This pairing mechanism predicts a large upturn in the NMR relaxation rate above T_{c}, a strong enhancement of Andreev reflection in tunneling measurements and an enhanced superconducting transition temperature T_{c} in Pu doped Np_{1-x}Pu_{x}Pd_{5}Al_{2}.Comment: This is a substantially revised version of the original paper, focussing on the high temperature heavy electron superconductors PuCoGa_5 and NpPd_5Al_2. A substantially revised supplementary online material to this paper can be found in arXiv 0710.1128v